Volume 26, Issue 6
Natural Products
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ChemInform Abstract: Reactions with and in Anhydrous Hydrogen Fluoride. Part 13. A Convenient One-Pot Synthesis of Glucofurano(2,1-d)oxazolines with an Additional 3,5,6-Orthoester Function.

R. MIETHCHEN

R. MIETHCHEN

Dep. Org. Chem., Univ. Rostock, D-18051 Rostock, Germany

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H. KLEIN

H. KLEIN

Dep. Org. Chem., Univ. Rostock, D-18051 Rostock, Germany

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C. PEDERSEN

C. PEDERSEN

Dep. Org. Chem., Univ. Rostock, D-18051 Rostock, Germany

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First published: February 7, 1995

Abstract

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ChemInform Abstract

Depending on the reaction conditions the sugar (I) gives oxazolines ( III) or (VI). (III) acts as glycosyl donor to give the methyl glycoside (V) without cleavage of the orthoester moiety.

chemical structure image

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