Preparative Organic Chemistry
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ChemInform Abstract: Thermal Rearrangements. Part 23. The Thermogram of a C6H6 Chemistry in the Temperature Range from 450 to 730 °C.
First published: February 7, 1995
Abstract
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ChemInform Abstract
Investigations on the thermal isomerization of 1,5-hexadiyne and its ( 1,6-D2)-labeled derivative reveal that the reaction products are formed by two different routes: electrocyclization to dimethylene cyclobutene at temp. up to 600 °C and radical reaction to benzene and pentafulvene at temp. above 550 °C.
