ChemInform Abstract: Chemistry of Extradiol Aromatic Ring Cleavage: Isolation of a Stable Dienol Ring Fission Intermediate and Stereochemistry of Its Enzymatic Hydrolytic Cleavage.
Abstract
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ChemInform Abstract
The extradiol cleavage of the aromatic compound (I) is investigated. The formal replacement of compound (III) from dienol (II) by a proton from water proceeds with retention of the stereochemistry.