Volume 25, Issue 40
Preparative Organic Chemistry
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ChemInform Abstract: Chemistry of Extradiol Aromatic Ring Cleavage: Isolation of a Stable Dienol Ring Fission Intermediate and Stereochemistry of Its Enzymatic Hydrolytic Cleavage.

W. W. Y. LAM

W. W. Y. LAM

Dep. Chem., Univ. Southampton, Southampton SO17 1BJ, UK

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T. D. H. BUGG

T. D. H. BUGG

Dep. Chem., Univ. Southampton, Southampton SO17 1BJ, UK

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First published: October 4, 1994

Abstract

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ChemInform Abstract

The extradiol cleavage of the aromatic compound (I) is investigated. The formal replacement of compound (III) from dienol (II) by a proton from water proceeds with retention of the stereochemistry.

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