Physical Inorganic Chemistry
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ChemInform Abstract: Alkaline Earth Transition Metal Antimonides M1M2 4Sb12 (M1: Ca, Sr, Ba; M2: Fe, Ru, Os) with LaFe4P12-Structure.
First published: October 4, 1994
Abstract
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ChemInform Abstract
The title compounds are prepared by solid state reaction of the corresponding alkaline earth metal antimonides with the transition metals at 660-800 °C (3 h, slow cooling to 600 °C, evacuated silica tube). Single crystal XRD data are presented for CaFe4Sb12, SrRu4Sb12, and BaRu4Sb12 (space group Im3, Z = 2, LaFe4P12- type structure).
