Volume 25, Issue 13
Isocyclic Compounds
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ChemInform Abstract: Synthesis of Naphthoquinone Derivatives. Part 13. A Novel Synthesis of Naphthazarin and Juglone Derivatives by Reaction of Naphthazarin and Juglone with Cyclic Enol Ethers.

Y. TANOUE

Y. TANOUE

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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A. TERADA

A. TERADA

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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H. TANIGUCHI

H. TANIGUCHI

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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T. OKUMA

T. OKUMA

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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H. KAAI

H. KAAI

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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M. ANAN

M. ANAN

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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Y. KAKARA

Y. KAKARA

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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M. DOI

M. DOI

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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S. MORISHITA

S. MORISHITA

Dep. Food Sci. Technol., Shimonoseki Univ. Fish., Shimonoseki, Yamaguchi 759-65, Japan

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First published: March 29, 1994

Abstract

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ChemInform Abstract

A new method to introduce a side chain into the benzene or quinone ring of naphthazarins, juglone as well as naphthols is described. The reaction with cyclic enol ethers such as (II) in the presence of BF3. times.Et2O gives derivatives like (III), (IV), (VI), (VII) and (IX).

chemical structure image

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