Preparative Organic Chemistry
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ChemInform Abstract: Three Consecutive Allylic Sigmatropic (S-O, S-S, S-C) Rearrangements of 1,8-Bis(allylthio)naphthalene Monooxides via Transannular Interaction.
First published: March 29, 1994
Abstract
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ChemInform Abstract
The mechanism for the multistep allylic rearrangement of the unstable sulfoxide (II) to give the allyl-substituted naphthodithiole (III) is investigated using the regiospecific deuterium-labelled derivative of ( II).
