Volume 25, Issue 12
Heterocyclic Compounds
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ChemInform Abstract: Functionalization at C-4 of a Heterocyclic Ketal Compound: 6,8- Dioxabicyclo(3.2.1)octane.

J.-G. JUN

J.-G. JUN

Dep. Chem., Hallym Univ., Chunchon 200-702, S. Korea

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First published: March 22, 1994

Abstract

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ChemInform Abstract

The functionalization of the title compound (X) is carried out via the carbinol (III) or by direct treatment of (X) with bromine. The products (V)/(VI), (VIII)/(IX) and (XI) (obtained as a single isomer, presumably the equatorial one) may be of interest as synthons in the preparation of natural compounds.

chemical structure image

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