ChemInform Abstract: Importance of Orbital and Electrostatic Interactions in Determining . pi.-Facial Selectivities in Nucleophilic Additions to endo-Substituted Bicyclo(2.2.2)octan-2-ones.
Abstract
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ChemInform Abstract
(study of 4 examples, reduction with NaBH4, (iBu)2AlH, and MeLi).