Heterocyclic Compounds
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ChemInform Abstract: Highly Stereoselective Addition Reactions of Metalated trans-1,3- Dithiane 1,3-Dioxide to Aldehydes.
First published: August 4, 1992
Abstract
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ChemInform Abstract
trans-1,3-Dithiane 1,3-dioxide (I) is converted into the sodium anion which is diastereoselectively coupled with the (hetero)aromatic aldehydes (II) to produce the alcohols (III). Further examples are described in the original paper.
