Volume 23, Issue 4
Preparative Organic Chemistry
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ChemInform Abstract: Acid Catalyzed Alcoholysis of an Epoxide and Reactions of Products on Contact with Silica Gel.

G. G. HABERMEHL

G. G. HABERMEHL

Chem. Inst., Tieraerztl. Hochsch. Hannover, W-3000 Hannover, Fed. Rep. Ger.

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I. WIPPERMANN

I. WIPPERMANN

Chem. Inst., Tieraerztl. Hochsch. Hannover, W-3000 Hannover, Fed. Rep. Ger.

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First published: January 28, 1992

Abstract

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ChemInform Abstract

Alcoholysis of the epoxide (I) in acidic MeOH leads to various products depending on the reaction conditions. One of these products, i.e. the ketone (III), rearranges to the isomeric ketone (VII) on contact with silica gel.

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