Preparative Organic Chemistry
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ChemInform Abstract: Thiocyanohydrins, a New Class of Compounds, Precursors of Unstabilized Thiocarbonyl Derivatives.
First published: October 1, 1991
Abstract
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ChemInform Abstract
Starting from the key compound (V), the mono- and dialkylated thiocyanohydrins (VIII) and (XI) are prepared by an alkylation- deprotection sequence under mild conditions. Furthermore, the use of thioacetonitrile (III) for the generation of unstable thioaldehyde ( XII) and thioformylcyanide (XIV) is demonstrated.
