Volume 22, Issue 39
Preparative Inorganic Chemistry
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ChemInform Abstract: Tetraphenylphosphonium Heptathiacyclo Thioarsenate(III), PPh4(SAsS7).

B. SIEWERT

B. SIEWERT

Fachbereich Chem., Univ., W-3550 Marburg, Fed. Rep. Ger.

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U. MUELLER

U. MUELLER

Fachbereich Chem., Univ., W-3550 Marburg, Fed. Rep. Ger.

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First published: October 1, 1991

Abstract

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ChemInform Abstract

The title thioarsenate, synthesized as outlined in the scheme, crystallizes in the orthorhombic space group Pna21 with Z = 4. The anion (SAsS7)- contains a AsS7 ring having the same crown conformation as S8.

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