ChemInform Abstract: Co2(CO)8-Catalyzed Reaction of Cyclic Ortho Esters with a Hydrosilane and Carbon Monoxide. Novel Method for Homologation of 1,2-, 1,3- and 1, 4-Diols.
Abstract
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ChemInform Abstract
Based on the reaction of the ester (VI) it is found, that the siloxymethylation occurs with inversion of configuration.