Volume 22, Issue 16
Organoelement Compounds
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ChemInform Abstract: Co2(CO)8-Catalyzed Reaction of Cyclic Ortho Esters with a Hydrosilane and Carbon Monoxide. Novel Method for Homologation of 1,2-, 1,3- and 1, 4-Diols.

N. CHATANI

N. CHATANI

Dep. Appl. Chem., Fac. Eng., Osaka Univ., Suita, Osaka 565, Japan

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Y. KAJIKAWA

Y. KAJIKAWA

Dep. Appl. Chem., Fac. Eng., Osaka Univ., Suita, Osaka 565, Japan

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H. NISHIMURA

H. NISHIMURA

Dep. Appl. Chem., Fac. Eng., Osaka Univ., Suita, Osaka 565, Japan

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S. MURAI

S. MURAI

Dep. Appl. Chem., Fac. Eng., Osaka Univ., Suita, Osaka 565, Japan

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First published: April 23, 1991

Abstract

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ChemInform Abstract

Based on the reaction of the ester (VI) it is found, that the siloxymethylation occurs with inversion of configuration.

chemical structure image

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