Physical Organic Chemistry
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ChemInform Abstract: Structure of a Highly Crowded Linear Trisilane.
First published: April 23, 1991
Abstract
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ChemInform Abstract
The title compound (I) (space group P21/c with Z = 4) is a photochemical source of highly hindered silylenes and silacyclobutadienes. The crowding around the central Si atom results in abnormally long Si-C and Si-Si bond lengths of this atom.
