Volume 22, Issue 15
Organoelement Compounds
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ChemInform Abstract: Silylzinc and Stannylzinc Compounds Containing Monodentate Phosphine Ligands.

H.-F. KLEIN

H.-F. KLEIN

Eduard-Zintl-Inst. Anorg. Chem., TH Darmstadt, W-6100 Darmstadt, Fed. Rep. Ger.

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J. MONTAG

J. MONTAG

Eduard-Zintl-Inst. Anorg. Chem., TH Darmstadt, W-6100 Darmstadt, Fed. Rep. Ger.

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U. ZUCHA

U. ZUCHA

Eduard-Zintl-Inst. Anorg. Chem., TH Darmstadt, W-6100 Darmstadt, Fed. Rep. Ger.

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First published: April 16, 1991

Abstract

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ChemInform Abstract

Ligand-free silylzinc or stannylzinc compounds rapidly react with oxygen or water and are light-sensitive. They are stabilized by phosphine coordination. The effect appears to be dominantly steric.

chemical structure image

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