Heterocyclic Compounds
Full Access
ChemInform Abstract: Synthesis and Metal-Binding Properties of Polybipyridine Ligands Derived from Acyclic and Macrocyclic Polyamines.
First published: November 27, 1990
Abstract
As shown for (III), synthetic procedures are developed for the preparation of ligands such as (III)-(VI) bearing up to six 2,2'-bipyridine groups attached to acyclic and macrocyclic polyamines.
ChemInform Abstract
As shown for (III), synthetic procedures are developed for the preparation of ligands such as (III)-(VI) bearing up to six 2,2'-bipyridine groups attached to acyclic and macrocyclic polyamines. The metal complexes of these ligands possess a variety of interesting chemical and physical properties. Ligand (IV) forms hemi-cage complexes with Ru(II), Fe(II), Cr(II) and Cr(III) cations and trinuclear complexes with (RuCl2(bpy)2) and (ReCl(CO)5). Hexapode (V) gives dinuclear complexes with Fe(II) salts.
