Preparative Organic Chemistry
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ChemInform Abstract: Selective Sulfurization of Olefins by 9,10-Epidithio-9,10-dihydroanthracene: Intermediacy of Diatomic Sulfur.
First published: November 27, 1990
Abstract
By reaction of (I) with HClO4 in the presence of olefins such as (III) and (IV) 1,2-dithiins such as (IV) and episulfides such as (VII) are obtained.
ChemInform Abstract
By reaction of (I) with HClO4 in the presence of olefins such as (III) and (IV) 1,2-dithiins such as (IV) and episulfides such as (VII) are obtained. This is explained in terms of generation of (II), which transfers singlet diatomic sulfur to olefins. A new method yielding singlet diatomic sulfur is developed.
