Organoelement Compounds
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ChemInform Abstract: Silylation of the Allylphosphonate Anion.
First published: November 20, 1990
Abstract
Treatment of the allylphosphonate (I) with lithium hexamethyldisilazide leads to the formation of allylphosphonate anions which are coupled in situ with trimethylchlorosilane (II) to give the 3-trimethylsilyl-1-propenylphosphonate (III).
ChemInform Abstract
Treatment of the allylphosphonate (I) with lithium hexamethyldisilazide leads to the formation of allylphosphonate anions which are coupled in situ with trimethylchlorosilane (II) to give the 3-trimethylsilyl-1-propenylphosphonate (III). This is converted to the bis(trimethylsilyl)allylphosphonate (IV) using the same procedure.
