ChemInform Abstract: Acid-Catalysed Dimerisation of Neolignans from Ratanhia. Assignment of Epimeric Configuration and Conformation of the Resulting Indanofuran Derivatives by 1H NMR Spectroscopy.
Abstract
Acid treatment of ratanhiaphenol II (I) affords the isoratanhiaphenols A-D (II) + (III) in a ratio of ca. 50:10:25:15.
ChemInform Abstract
Acid treatment of ratanhiaphenol II (I) affords the isoratanhiaphenols A-D (II) + (III) in a ratio of ca. 50:10:25:15. Acid dimerisation of conocarpan (IV), however, gives only an inseparable mixture of epimers (Va + b). The dimers show lower antibacterial activity than that of the parent compounds (I) and (IV).