Organoelement Compounds
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ChemInform Abstract: Iridium Thioether Chemistry: The Synthesis and Structures of (IrL2)(PF6)3 and (IrHL2)(PF6)2 (L: 1,4,7-trithiacyclononane).
First published: September 11, 1990
Abstract
The hydrido complex (III) crystallizes as its hexafluorophosphate-bis-nitromethane solvate in the space group Cc with Z=4.
ChemInform Abstract
The hydrido complex (III) crystallizes as its hexafluorophosphate-bis-nitromethane solvate in the space group Cc with Z=4. Treatment of (III) with HNO3 under reflux affords (IV) (space group C2/c, Z=4), thus transforming the bidentate ligand to a tridentate one. The redox properties of this homoleptic thioether complex are discussed and compared to those of the rhodium analogue.
