Organoelement Compounds
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ChemInform Abstract: The First Heteronuclear Monoazadiene Complex: Synthesis and X-Ray Crystal Structure of HFeRu(CO)5(R-C=CH-CH=N-iPr), Isolobally Related to HFe(CO)2(η5-C5H5).
First published: September 11, 1990
Abstract
The photochemical reaction of (I) with Fe2(CO)9 (II) gives unexpectedly the novel compounds (III).
ChemInform Abstract
The photochemical reaction of (I) with Fe2(CO)9 (II) gives unexpectedly the novel compounds (III). They are interesting because of their heteronuclear character, which is unprecedented in the chemistry of monoazadiene ligands. The structure is confirmed by an X-ray analysis of (IIIb) (space group P21/c, Z=4).
