Volume 21, Issue 37
Isocyclic Compounds
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ChemInform Abstract: Selective Synthesis of N-(Cyclohexylmethyl)-N-alkylamines from Primary Amines and Pimelaldehyde Using Tetracarbonylhydridoferrate, HFe(CO)4-, as a Reducing Reagent.

S. C. SHIM

S. C. SHIM

Dep. Ind. Chem., Kyungpook Natl. Univ., Taegu 702-701, Korea

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Y. G. KWON

Y. G. KWON

Dep. Ind. Chem., Kyungpook Natl. Univ., Taegu 702-701, Korea

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C. H. DOH

C. H. DOH

Dep. Ind. Chem., Kyungpook Natl. Univ., Taegu 702-701, Korea

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H. S. KIM

H. S. KIM

Dep. Ind. Chem., Kyungpook Natl. Univ., Taegu 702-701, Korea

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T. J. KIM

T. J. KIM

Dep. Ind. Chem., Kyungpook Natl. Univ., Taegu 702-701, Korea

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First published: September 11, 1990

Abstract

The amines (I) react with pimelaldehyde (II) in the presence of CO and tetracarbonylhydridoferrate generated in situ from Fe(CO)5 and KOH to form the cyclohexylmethylamines (III).

ChemInform Abstract

The amines (I) react with pimelaldehyde (II) in the presence of CO and tetracarbonylhydridoferrate generated in situ from Fe(CO)5 and KOH to form the cyclohexylmethylamines (III). (Further examples are given in the original paper).

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