Volume 21, Issue 37
Preparative Organic Chemistry
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ChemInform Abstract: Experimental Evidence for 1,2-Fluorine Atom Migration in Tritiated 1,1,2-Trifluoroethyl Radical.

M. KOTAKA

M. KOTAKA

Res. Lab. Nucl. React., Tokyo Inst. Technol., Meguro, Tokyo 152, Jap.

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T. KOHIDA

T. KOHIDA

Res. Lab. Nucl. React., Tokyo Inst. Technol., Meguro, Tokyo 152, Jap.

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S. SATO

S. SATO

Res. Lab. Nucl. React., Tokyo Inst. Technol., Meguro, Tokyo 152, Jap.

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First published: September 11, 1990

ChemInform Abstract

Recoil 3H atoms formed by the 3He(n,p)T nuclear reaction in gaseous mixtures of CF2=CHF + He generate products containing -CH2-CF3 groups such as CH3-CF3 and CF3-CH2-CH2-CF3, thus evidencing fluorine migration.

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