Volume 21, Issue 37
Preparative Organic Chemistry
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ChemInform Abstract: New Low-Valent Titanium Reagents for Dicarbonyl Coupling and Their Use in a General Method of Annulation.

D. L. J. CLIVE

D. L. J. CLIVE

Chem. Dep., Univ. Alberta, Edmonton, Alberta T6G 2G2, Canada

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K. S. K. MURTHY

K. S. K. MURTHY

Chem. Dep., Univ. Alberta, Edmonton, Alberta T6G 2G2, Canada

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C. ZHANG

C. ZHANG

Chem. Dep., Univ. Alberta, Edmonton, Alberta T6G 2G2, Canada

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W. D. HAYWARD

W. D. HAYWARD

Chem. Dep., Univ. Alberta, Edmonton, Alberta T6G 2G2, Canada

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S. DAIGNEAULT

S. DAIGNEAULT

Chem. Dep., Univ. Alberta, Edmonton, Alberta T6G 2G2, Canada

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First published: September 11, 1990

Abstract

The keto aldehydes and diketones (I), (III), (V), and (VII) are reductively cyclized with a low-valent titanium reagent to produce the fused cycloalkenes (II), (IV), (VI), or (VIII).

ChemInform Abstract

The keto aldehydes and diketones (I), (III), (V), and (VII) are reductively cyclized with a low-valent titanium reagent to produce the fused cycloalkenes (II), (IV), (VI), or (VIII). Further examples are given in the original paper.

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