Organoelement Compounds
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ChemInform Abstract: Synthesis and Characterization of Cobalt(III) Complexes Containing α-Diamine and Carbinolamine Derived from α-Aminomalonate and Ethylenediamine.
First published: May 29, 1990
Abstract
The α-aminomalonate ion undergoes a C-N bond formation with (I) affording in MeOH under air a mixture of (III), (IV) and (V) with no selectivity.
ChemInform Abstract
The α-aminomalonate ion undergoes a C-N bond formation with (I) affording in MeOH under air a mixture of (III), (IV) and (V) with no selectivity. The same reaction under N2 gives preferentially the α-diamine complex (IV), whereas the reaction in water under air yields predominantly the novel carbinolamine complex (V) (12% yield). The X-ray structure of (IV) as its chloride salt is determined (P1, Z=4).
