Volume 21, Issue 1
Preparative Organic Chemistry
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ChemInform Abstract: Binaphthol as a Chiral Auxiliary. Asymmetric Alkylation of Arylacetic Acid.

K. FUJI

K. FUJI

Inst. Chem. Res., Kyoto Univ., Uji, Kyoto 611, Japan

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M. NODE

M. NODE

Inst. Chem. Res., Kyoto Univ., Uji, Kyoto 611, Japan

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F. TANAKA

F. TANAKA

Inst. Chem. Res., Kyoto Univ., Uji, Kyoto 611, Japan

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S. HOSOI

S. HOSOI

Inst. Chem. Res., Kyoto Univ., Uji, Kyoto 611, Japan

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First published: January 2, 1990

ChemInform Abstract

The binaphthyl phenylacetates (I) are deprotonated and then alkylated with the halides (II), yielding predominantly the diastereomers (III).

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