Volume 21, Issue 1
Physical Inorganic Chemistry
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ChemInform Abstract: Electrosynthesis and Photoelectroactivity of Polycrystalline p-Type Cadmium Selenide.

K. SINGH

K. SINGH

Chem. Dep., Gorakhpur Univ., Gorakhpur 273 009

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D. N. UPADHYAY

D. N. UPADHYAY

Chem. Dep., Gorakhpur Univ., Gorakhpur 273 009

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V. K. PANDEY

V. K. PANDEY

Chem. Dep., Gorakhpur Univ., Gorakhpur 273 009

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First published: January 2, 1990

Abstract

Photoelectroactivity data obtained using a CdSe/TiO2 film electrode, prepared by electrochemical codeposition from 0.1 M CdCl2 + 0.01 M SeO2, and a CdSe pellet under identical experimental conditions are clearly indicative of p-type semiconductivity for the CdSe film.

ChemInform Abstract

Photoelectroactivity data obtained using a CdSe/TiO2 film electrode, prepared by electrochemical codeposition from 0.1 M CdCl2 + 0.01 M SeO2, and a CdSe pellet under identical experimental conditions are clearly indicative of p-type semiconductivity for the CdSe film. This result is supported by current-voltage data as well as by the photoelectrochemical characteristics of a hetero-junction PEC formed by the p-CdSe electrode combined with an n-CdSe electrode. The film exhibits reasonable stability although its activity is not attractive. Nevertheless it can be combined with an n-CdSe electrode to obtain enhanced photoresponsiveness.

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