Isocyclic Compounds
Full Access
ChemInform Abstract: Hydroxyquinone Anellation.
First published: December 12, 1989
Abstract
The siloxyenones (I) are coupled with the lithiated allene (II) to produce the carbinols (III) which are desilylated and subsequently epoxidized to give the oxiranes (IV).
ChemInform Abstract
The siloxyenones (I) are coupled with the lithiated allene (II) to produce the carbinols (III) which are desilylated and subsequently epoxidized to give the oxiranes (IV). These are cyclized upon treatment with a base and then methylated with diazomethane (V) to yield the methoxyquinones (VI).
