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ChemInform Abstract: Cyclopeptide Alkaloid Model Studies. A Two-Step Conversion of 5-Aminoisoxazoles to Amino Acid Bisamides.
First published: May 30, 1989
Abstract
Thermolysis of the 5-(dibenzylamino)isoxazoles (III) results in rearrangement, producing the azirinecarboxamides (VIII).
ChemInform Abstract
Thermolysis of the 5-(dibenzylamino)isoxazoles (III) results in rearrangement, producing the azirinecarboxamides (VIII). Hydrative cleavage of these with potassium trimethylsilyloxide or tetrabutylammonium hydroxide gives the bisamides (IX), together with the imino derivatives (X).
