Organoelement Compounds
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ChemInform Abstract: Multiple Bonds Between Main-Group Elements and Transition Metals. Part 60. Bridging Lead Atoms in Organometallic Complexes: First Examples.
First published: May 30, 1989
Abstract
The Pb-bridged Mn2 complexes (III) are obtained by equimolar reaction of the photochemically generated THF-Mn complex (I) with PbCl2 (II).
ChemInform Abstract
The Pb-bridged Mn2 complexes (III) are obtained by equimolar reaction of the photochemically generated THF-Mn complex (I) with PbCl2 (II). Further reaction of (IIIb) with (Ib) yields the Mn3Pb complex (IV) which is isolobal with methylene cyclopropane. The structures of the Mn2Pb complex (IIIa) (space group I42d, Z = 8) and Mn3Pb complex (IV) (P1, Z=2) are determined by X-ray analysis.
