Volume 20, Issue 22
Organoelement Compounds
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ChemInform Abstract: Hydrosilylation of N- and O-Heterocyclic Aldehydes in the Presence of Rh(I), Ru(II), and Pd(II) Complexes.

I. G. IOVEL'

I. G. IOVEL'

Inst. org. sint. AN Latv. SSR, Riga 226006

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YU. SH. GOL'DBERG

YU. SH. GOL'DBERG

Inst. org. sint. AN Latv. SSR, Riga 226006

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A. P. GAUKHMAN

A. P. GAUKHMAN

Inst. org. sint. AN Latv. SSR, Riga 226006

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M. P. GAVARS

M. P. GAVARS

Inst. org. sint. AN Latv. SSR, Riga 226006

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M. V. SHIMANSKAYA

M. V. SHIMANSKAYA

Inst. org. sint. AN Latv. SSR, Riga 226006

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E. LUKEVITS

E. LUKEVITS

Inst. org. sint. AN Latv. SSR, Riga 226006

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First published: May 30, 1989

Abstract

Hydrosilylation of the aldehydes (I) with triethylsilane (II) in the presence of Rh(I), Ru(II), or Pd(II) complexes gives the silyl ether (III) and the dimer (IV).

ChemInform Abstract

Hydrosilylation of the aldehydes (I) with triethylsilane (II) in the presence of Rh(I), Ru(II), or Pd(II) complexes gives the silyl ether (III) and the dimer (IV). Yield and product ratio widely depend on the starting aldehyde and the reaction conditions.

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