ChemInform Abstract: Isolation and Alcoholysis of an ipso-Adduct, Vinylidenecyclohexadiene from Photolysis of 1-(p-Ethoxyphenyl)vinyl Bromide.
Abstract
The vinylic bromide (I) mentioned in the title is irradiated in the presence of sodium ethoxide (II), yielding the vinylidene cyclohexadiene (III).
ChemInform Abstract
The vinylic bromide (I) mentioned in the title is irradiated in the presence of sodium ethoxide (II), yielding the vinylidene cyclohexadiene (III). Alcoholysis of this allene (III) produces the triphenylvinyl ethers (V).