Volume 20, Issue 22
Isocyclic Compounds
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ChemInform Abstract: Isolation and Alcoholysis of an ipso-Adduct, Vinylidenecyclohexadiene from Photolysis of 1-(p-Ethoxyphenyl)vinyl Bromide.

T. KITAMURA

T. KITAMURA

Dep. Appl. Chem., Fac. Eng., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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T. KABASHIMA

T. KABASHIMA

Dep. Appl. Chem., Fac. Eng., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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S. KOBAYASHI

S. KOBAYASHI

Dep. Appl. Chem., Fac. Eng., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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H. TANIGUCHI

H. TANIGUCHI

Dep. Appl. Chem., Fac. Eng., Kyushu Univ., Hakozaki, Fukuoka 812, Japan

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First published: May 30, 1989

Abstract

The vinylic bromide (I) mentioned in the title is irradiated in the presence of sodium ethoxide (II), yielding the vinylidene cyclohexadiene (III).

ChemInform Abstract

The vinylic bromide (I) mentioned in the title is irradiated in the presence of sodium ethoxide (II), yielding the vinylidene cyclohexadiene (III). Alcoholysis of this allene (III) produces the triphenylvinyl ethers (V).

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