Preparative Organic Chemistry
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ChemInform Abstract: Noncatalyzed, Homogeneously Catalyzed, and Heterogeneously Catalyzed Formyl Formation.
First published: May 30, 1989
Abstract
Potential energy surfaces are calculated for H migration onto a carbonyl to give a formyl structure for a noncatalyzed and two catalyzed (homogeneously and heterogeneously) reactions (see scheme) using a semiempirical MINDO procedure.
ChemInform Abstract
Potential energy surfaces are calculated for H migration onto a carbonyl to give a formyl structure for a noncatalyzed and two catalyzed (homogeneously and heterogeneously) reactions (see scheme) using a semiempirical MINDO procedure. The differences of the same process in different systems and the consequences of the explicit comparison of homogeneous and heterogeneous catalysis are discussed.
