Physical Organic Chemistry
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ChemInform Abstract: The Effect of the Nature of the Lowest Unoccupied Molecular Orbital (LUMO) of Some Arylmethylsulfonium Salt Derivatives on Photochemical and Redox Behavior.
First published: May 30, 1989
Abstract
Fluorescence quantum yield, excited singlet state lifetimes, and electrochemical peak potentials for reduction of (I) and (II) support the conclusion from MO calculations that the nature of the LUMO switches from σ* to π* for (Ib) and (IIb).
ChemInform Abstract
Fluorescence quantum yield, excited singlet state lifetimes, and electrochemical peak potentials for reduction of (I) and (II) support the conclusion from MO calculations that the nature of the LUMO switches from σ* to π* for (Ib) and (IIb). (Accordance with previous photochemical results).
