Volume 20, Issue 22
Physical Inorganic Chemistry
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ChemInform Abstract: Enhancement of Catalytic Activity of Copper Ion-Exchanged Y Type Zeolites for the Decomposition of Nitrogen Monoxide.

M. IWAMOTO

M. IWAMOTO

Dep. Ind. Chem., Fac. Eng., Miyazaki Univ., Miyazaki 889-21

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H. YAHIRO

H. YAHIRO

Dep. Ind. Chem., Fac. Eng., Miyazaki Univ., Miyazaki 889-21

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T. KUTSUNO

T. KUTSUNO

Dep. Ind. Chem., Fac. Eng., Miyazaki Univ., Miyazaki 889-21

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S. BUNYU

S. BUNYU

Dep. Ind. Chem., Fac. Eng., Miyazaki Univ., Miyazaki 889-21

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S. KAGAWA

S. KAGAWA

Dep. Ind. Chem., Fac. Eng., Miyazaki Univ., Miyazaki 889-21

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First published: May 30, 1989

Abstract

Catalytic decomposition of NO over partially Cu(II)-exchanged Y zeolites (CuY) is the simplest method for removal of harmful NO because any reducing agents or absorbents are not necessary.

ChemInform Abstract

Catalytic decomposition of NO over partially Cu(II)-exchanged Y zeolites (CuY) is the simplest method for removal of harmful NO because any reducing agents or absorbents are not necessary. This process is shown to be enhanced by additional loading of the zeolite with Co3+ or Ni2+ ions or by evacuation treatment around 923-973 K. The catalytic activity of CuY evacuated at 973 K is twice that of untreated CuY. Partial exchange with Ca2+, Mn2+, Fe2+, and Zn2+ diminishes the catalytic activity.

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