Volume 20, Issue 18
Natural Products
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ChemInform Abstract: An Efficient Route to Homologated Pyranosidic Conjugated Enals.

C. BURNOUF

C. BURNOUF

Inst. Chim. Subst. Nat. CNRS, 91198 Gif-sur-Yvette, France

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J. C. LOPEZ

J. C. LOPEZ

Inst. Chim. Subst. Nat. CNRS, 91198 Gif-sur-Yvette, France

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M. DE LOS A. LABORDE

M. DE LOS A. LABORDE

Inst. Chim. Subst. Nat. CNRS, 91198 Gif-sur-Yvette, France

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A. OLESKER

A. OLESKER

Inst. Chim. Subst. Nat. CNRS, 91198 Gif-sur-Yvette, France

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G. LUKACS

G. LUKACS

Inst. Chim. Subst. Nat. CNRS, 91198 Gif-sur-Yvette, France

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First published: May 2, 1989

Abstract

Various transformations of pyranosides are described, forming the homologous enals which are useful in hetero Diels-Alder cycloadditions for the synthesis of C-glycosides.

ChemInform Abstract

Various transformations of pyranosides are described, forming the homologous enals which are useful in hetero Diels-Alder cycloadditions for the synthesis of C-glycosides. The conversion of the enol ether (I) to the enal (II) by treatment with pyridinium chloride is outlined in the reaction scheme. Further examples are given in the original paper.

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