Volume 20, Issue 18
Preparative Organic Chemistry
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ChemInform Abstract: Diazepines. Part 27. Effects of Substituents on the Bromination of 2,3-Dihydro-1,4-diazepinium Salts.

A. R. BUTLER

A. R. BUTLER

Dep. Chem., Univ. St. Andrews, St. Andrews, Fife, UK KY16 9ST

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D. LLOYD

D. LLOYD

Dep. Chem., Univ. St. Andrews, St. Andrews, Fife, UK KY16 9ST

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H. MCNAB

H. MCNAB

Dep. Chem., Univ. St. Andrews, St. Andrews, Fife, UK KY16 9ST

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D. R. MARSHALL

D. R. MARSHALL

Dep. Chem., Univ. St. Andrews, St. Andrews, Fife, UK KY16 9ST

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K. S. TUCKER

K. S. TUCKER

Dep. Chem., Univ. St. Andrews, St. Andrews, Fife, UK KY16 9ST

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First published: May 2, 1989

ChemInform Abstract

The rate of bromination at the 6-position of (I) or at the p-position of the 6-phenyl group in (II) decreases in the order shown due to steric hindrance (16 further examples are studied).

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