Volume 20, Issue 6
Preparative Organic Chemistry
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ChemInform Abstract: Selective Synthesis of Dimethylamine Over Small-Pore Zeolites. Part 2. Effects of Impurities on Catalytic Properties of H-RHO.

R. D. SHANNON

R. D. SHANNON

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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M. JUN. KEANE

M. JUN. KEANE

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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L. ABRAMS

L. ABRAMS

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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R. H. STALEY

R. H. STALEY

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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T. E. GIER

T. E. GIER

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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D. R. CORBIN

D. R. CORBIN

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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G. C. SONNICHSEN

G. C. SONNICHSEN

Cent. Res. Dev. Dep., E. I. du Pont de Nemours&Co., Exp. Stn., Wilmington, DE 19898, USA

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First published: February 7, 1989

Abstract

Impurities of zeolite RHO such as unreacted H-gel, H-chabazite, H-Pc, and H-pollucite are prepared and their effect on the dimethylamine synthesis from MeOH and NH3 is studied.

ChemInform Abstract

Impurities of zeolite RHO such as unreacted H-gel, H-chabazite, H-Pc, and H-pollucite are prepared and their effect on the dimethylamine synthesis from MeOH and NH3 is studied. None of these phases is as reactive or selective as H-RHO.

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