Volume 20, Issue 2
Preparative Organic Chemistry
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ChemInform Abstract: Carboxylic Acid Anhydrides as Acylating Agents in the Synthesis of Isothiocyanates.

B. A. TROFIMOV

B. A. TROFIMOV

Inst. Pharm. Chem., Univ., D-3550 Marburg/Lahn

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N. A. NEDOLYA

N. A. NEDOLYA

Inst. Pharm. Chem., Univ., D-3550 Marburg/Lahn

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N. P. PAPSHEVA

N. P. PAPSHEVA

Inst. Pharm. Chem., Univ., D-3550 Marburg/Lahn

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V. V. GERASIMOVA

V. V. GERASIMOVA

Inst. Pharm. Chem., Univ., D-3550 Marburg/Lahn

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M. G. VORONKOV

M. G. VORONKOV

Inst. Pharm. Chem., Univ., D-3550 Marburg/Lahn

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First published: January 10, 1989

ChemInform Abstract

The reaction between the vinyloxyamine (I), CS2 (II) and NEt3 affords triethylammonium 2-vinyloxyethyldithiocarbamate which is acylated in situ by carboxylic acid anhydrides, as e.g. acetanhydride, to yield the desired product (III).

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