Volume 19, Issue 18
Isocyclic Compounds
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ChemInform Abstract: 3-Fluoro-3-trifluoromethyldiazirine.

W. P. DAILEY

W. P. DAILEY

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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First published: May 3, 1988

Abstract

Trifluoroacetamidine (I) is oxidatively brominated to produce the bromo(trifluoromethyl)aziridine (II) which is converted to the fluoride (III).

ChemInform Abstract

Trifluoroacetamidine (I) is oxidatively brominated to produce the bromo(trifluoromethyl)aziridine (II) which is converted to the fluoride (III). Thermolysis of (III) in the presence of tetramethylethene (IV) yields the cyclopropane (V).

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