Volume 19, Issue 4
Natural Products
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ChemInform Abstract: Regio- and Stereo-Selective Synthesis of (2E,6E,8E)-N-(2-Methylpropyl)-2,6,8-hexadecatrien-10-ynamide, a Naturally-Occurring Acetylenic Substance.

A. CARPITA

A. CARPITA

Dip. Chim. Chim. Ind., Univ. Pisa, I-56100 Pisa, Italy

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D. NERI

D. NERI

Dip. Chim. Chim. Ind., Univ. Pisa, I-56100 Pisa, Italy

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R. ROSSI

R. ROSSI

Dip. Chim. Chim. Ind., Univ. Pisa, I-56100 Pisa, Italy

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First published: January 26, 1988

Abstract

The intermediate borane (VII) is used as a key compound for two different synthetic pathways which lead to the desired product (VIII).

ChemInform Abstract

The intermediate borane (VII) is used as a key compound for two different synthetic pathways which lead to the desired product (VIII). The latter is subsequently converted via the ester (XII) to the title compound (XIV), a constituent of Achillea ageratifolia.

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