Organoelement Compounds
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ChemInform Abstract: Reaction of Ethyl Trimethylsilyl Diethoxymethylphosphonite with Carbonyl Compounds.
First published: January 26, 1988
Abstract
The phosphonite (I) reacts with butyraldehyde (IIa) or benzaldehyde (IIb) to give the phosphinates (III).
ChemInform Abstract
The phosphonite (I) reacts with butyraldehyde (IIa) or benzaldehyde (IIb) to give the phosphinates (III). Treatment of (I) with methyl acrylate (IV) produces the C-silylated phosphinate (V), together with small amounts of the phosphinate (VI). The latter isomerizes upon distillation, forming (V).
