Organoelement Compounds
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ChemInform Abstract: The Reaction of (Trifluoromethyl)dialkylaminoboranes with HF, HCl, and HBr. X-Ray Structure Investigation of the Aminoboranes (CF3)2B(X)NHMe2, X = F and OH.
First published: January 12, 1988
Abstract
Condensing dry hydrogen chloride or hydrogen bromide into a ethereal solution of (I) yields the boronium salts (II).
ChemInform Abstract
Condensing dry hydrogen chloride or hydrogen bromide into a ethereal solution of (I) yields the boronium salts (II). Hydrogen fluoride and (I) produce the difluoroborane dimethylamine complex (III). Reaction of bis(trifluoromethyl)dimethylaminoborane (IV) with water or hydrogen halides gives the borane dimethylamine complexes (V).
