Volume 19, Issue 2
Heterocyclic Compounds
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ChemInform Abstract: Synthesis of 1,2,4-Triazoles and 4-Amino-1,2,4-δ2-triazolines from Azines and Nitrilimines.

L. P. VASIL'EVA

L. P. VASIL'EVA

Leningradskii tekhnol. inst. tsellyul.-bum. prom'st.

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G. S. AKIMOVA

G. S. AKIMOVA

Leningradskii tekhnol. inst. tsellyul.-bum. prom'st.

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V. N. CHISTOKLETOV

V. N. CHISTOKLETOV

Leningradskii tekhnol. inst. tsellyul.-bum. prom'st.

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First published: January 12, 1988

Abstract

The reactions between the azines (I) and the nitrilimines (II), bearing electron-withdrawing substituents, yield the 1,2,4-Δ2-triazolines (III), whereas the aldazines (IV), on reaction with the diarylazines (V), give the 1,2,4-triazoles (VI).

ChemInform Abstract

The reactions between the azines (I) and the nitrilimines (II), bearing electron-withdrawing substituents, yield the 1,2,4-Δ2-triazolines (III), whereas the aldazines (IV), on reaction with the diarylazines (V), give the 1,2,4-triazoles (VI). Finally, the aldazine (IVa) is found to react with the nitrilimines (IIa) to give the 1,2,4-Δ2-triazolines (VII).

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