Isocyclic Compounds
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ChemInform Abstract: Reaction of 2-Aryl-3-(N,N-dimethylamino)-1-propenes and Their Corresponding Quaternary Ammonium Salts with Organometallic Species and Reducing Agents.
First published: January 12, 1988
Abstract
Reaction of the methoxyphenyldimethylaminopropene (I) with the organometallic compounds (II) gives the styrenes (IIIb) and (IIIc).
ChemInform Abstract
Reaction of the methoxyphenyldimethylaminopropene (I) with the organometallic compounds (II) gives the styrenes (IIIb) and (IIIc). (IIIa) is prepared by addition of methylmagnesium bromide (IIa) to the methoxyphenylpropenylammonium iodide (IV), followed by elimination. The alkene (VI) is obtained by reaction of (IV) with the cuprate (IIb) (M: Cu(Li)Bu) or by reduction of (IV).
