Preparative Organic Chemistry
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ChemInform Abstract: The Chemistry of Diacyl Peroxides. Part 8. The Reactions between Polyfluorodiacyl Peroxides and 2-Nitro-2-nitrosopropane. Generation of Bis-(polyfluoroalkyl) Nitroxides.
First published: December 8, 1987
Abstract
2-Nitro-2-nitrosopropane (I) decomposes to give predominantly acetone (II), while in the presence of a large excess of the polyfluorodiacyl peroxides (VI), the 2,2-dinitropropane (IV) is the main product.
ChemInform Abstract
2-Nitro-2-nitrosopropane (I) decomposes to give predominantly acetone (II), while in the presence of a large excess of the polyfluorodiacyl peroxides (VI), the 2,2-dinitropropane (IV) is the main product. In this case, the nitroxides (VIII) are also formed as by-products, together with (II) and (VII). (Mechanism, kinetic, ESR-data).
