Isocyclic Compounds
Full Access
ChemInform Abstract: Synthesis of β,β-Disubstituted Acyclic α-Enones with an Asymmetric Carbon.
First published: September 22, 1987
Abstract
The Grignard compound (I) is coupled with the E-styryl ketones (II), producing the saturated ketones (III).
ChemInform Abstract
The Grignard compound (I) is coupled with the E-styryl ketones (II), producing the saturated ketones (III). These are converted to the α-phenylselenenyl ketones (V) which undergo dehydroselenenylation without previous purification, forming E/Z-mixtures of the racemic α-enones (VI).
