Physical Inorganic Chemistry
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ChemInform Abstract: Kinetics of the Formation and Hydrolysis Reactions of Some Thiomolybdate(VI) Anions in Aqueous Solution.
First published: September 22, 1987
Abstract
The kinetics of the formation of the anions (II) and (III) have been determined spectroscopically (UV/VIS) by addition of excess sulfide to (I) in buffered (pH 6-8) aqueous solution.
ChemInform Abstract
The kinetics of the formation of the anions (II) and (III) have been determined spectroscopically (UV/VIS) by addition of excess sulfide to (I) in buffered (pH 6-8) aqueous solution. The reverse hydrolysis reactions are measured under the same conditions. Values for the rate constants k1, k2, k3, k4, and k5 (see scheme) obtained at pH 7 are given. Reaction mechanisms are briefly discussed.
