Volume 18, Issue 35
Heterocyclic Compounds
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ChemInform Abstract: Hydrogenation and Hydrosilylation of Quinoxaline by Homogeneous Rhodium Catalysts.

S. MURATA

S. MURATA

Dep. Chem., Coll. General Educ., Univ., Nagoya 464, Japan

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T. SUGIMOTO

T. SUGIMOTO

Dep. Chem., Coll. General Educ., Univ., Nagoya 464, Japan

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S. MATSUURA

S. MATSUURA

Dep. Chem., Coll. General Educ., Univ., Nagoya 464, Japan

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First published: September 1, 1987

Abstract

Homogeneous hydrogenation and hydrosilylation of the 2-methylquinoxaline (I) is achieved in the presence of the rhodium catalyst (II), producing the methyltetrahydroquinoxaline (III) and the bissilyl derivative (V) which is desilylated, directly forming (III).

ChemInform Abstract

Homogeneous hydrogenation and hydrosilylation of the 2-methylquinoxaline (I) is achieved in the presence of the rhodium catalyst (II), producing the methyltetrahydroquinoxaline (III) and the bissilyl derivative (V) which is desilylated, directly forming (III). (1H-NMR-data).

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