Volume 18, Issue 35
Heterocyclic Compounds
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ChemInform Abstract: Some Pecularities in the Synthesis of Spirocyclic Orthoesters.

N. V. ZHIDKOVA

N. V. ZHIDKOVA

Inst. khim. fiz. AN SSSR, Moskva

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L. N. TUROVSKAYA

L. N. TUROVSKAYA

Inst. khim. fiz. AN SSSR, Moskva

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V. M. KOBRYANSKII

V. M. KOBRYANSKII

Inst. khim. fiz. AN SSSR, Moskva

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G. M. TROFIMOVA

G. M. TROFIMOVA

Inst. khim. fiz. AN SSSR, Moskva

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D. D. NOVIKOV

D. D. NOVIKOV

Inst. khim. fiz. AN SSSR, Moskva

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First published: September 1, 1987

ChemInform Abstract

The role of a primary complex formation with the catalyst is deduced from a kinetic study of the boron trifluoride-catalyzed reaction of γ-butyrolactone (I) with the epoxides (II), which gives the spirocyclic orthoesters (III).

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